Temperature effects on the structure of liquid D-methanol through neutron diffraction

Pramana

S Sarkar²  A Sahoo²  R N Joarder1²  P S R Krishna¹ 

[1] Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085, India$$;Department of Physics, Jadavpur University, Kolkata 700 032, India$$

关键词: Structure;    correlation;    D-methanol;    neutron diffraction.;   

DOI  :  

学科分类：物理（综合）

来源: Indian Academy of Sciences

【 摘 要 】

The study of changes in the structure (H-bonded) of liquid alcohols at elevated temperatures is rare probably due to low flash points of these liquids. An indigenously devised special quartz cell is now used to carry out the structural studies of these liquids at elevated temperatures through neutron diffraction. Here, the liquid consists of deuterated methanol and neutron data was collected on the high-𝑄 diffractometer at Dhruva, BARC. The corrected data at elevated temperatures (BP (boiling point) and double the BP) show that there is a large change in the H-bonded structure of this liquid. The pre-peak or hump, known to be signature of H-bonded clusters appears to be present at all the three temperatures studied. In the low-𝑄 (scattering vector) data Ornstein-Zernike (OZ) behaviour is also observed. It is, however, seen that the intramolecular structure does not change very much at higher temperatures. A detailed model analysis is in progress and would be reported later.

【 授权许可】

Unknown