Pressure induced phase transition behaviour in 𝑓-electron based dialuminides

Pramana

N V Chandra Shekar¹  P Ch Sahu1¹ 

[1] Materials Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, India$$

关键词: High pressure;    x-ray diffraction;    actinides and rare-earths;    dialuminides;    phase transition;   

DOI  :  

学科分类：物理（综合）

来源: Indian Academy of Sciences

【 摘 要 】

The rare-earth and actinide based compounds are endowed with several exotic physical and chemical properties due to the presence of 𝑓-electrons. These properties exhibit interesting changes under the action of various thermodynamic fields and hence continues to be a subject of extensive research. For instance, under pressure, the nature of 𝑓-electrons can be changed from localized to itinerant, leading to a variety of changes in their structural, physical and chemical properties. The present review on the high pressure phase transition behaviour of dialuminides of rare earths and actinides is an outcome of research in our laboratory during the last five years using a unique combination of a Guinier diffractometer and a diamond anvil cell built in-house. To bring out the correlations between the compressibility and structural behaviour with the electronic structure, we have also carried out electronic structure calculation. Further, the usefulness of Villars' three parameter structure maps in predicting pressure induced structural transitions has been explored and this has been illustrated with the available phase transition data.

【 授权许可】

Unknown