Development of Palladium, Gold and Gold-Palladium Containing Metal-Carbon Nanoreactors: Hydrogen Adsorption

Bulletin of the Korean chemical society

Suranjana V. Mayani¹  Vishal J. Mayani¹  Sang Wook Kim¹ 

关键词: Carbon cage;    Hydrogen adsorption;    Metal carbon nanoreactors;    Metal-doped;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Metal-carbon nanoreactors (MCNRs) were prepared from a pristine carbon cage (CC) using a simple and efficient template method with nano silica ball (NSB), pyrolysis fuel oil (PFO) and transition metals, such as palladium and gold. Metal nanoparticles were embedded in approximately 25 and 170 nm sized, highly ordered carbon cages. The newly developed Pd, Au and Au–Pd doped carbon nanoreactors were characterized by microanalysis, N2 adsorption–desorption isotherm, powder X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS), transmission electron microscopy and inductively coupled plasma (ICP) analysis. The ordered MCNRs have exhibited dynamic hydrogen adsorption capability compared to the carbon cage.

【 授权许可】

Unknown