Novel and Chemoselective Dehydrogenation of 3,4-Dihydropyrimidin-2(1H)-ones with 1,4-Bis(triphenylphosphonium)-2-butene Peroxodisulfate

Bulletin of the Korean chemical society

Maryam Gorjizadeh¹ 

关键词: Dehydrogenation;    Pyrimidin-2(1H)-ones;    3;    4-Dihydropyrimidin-2(1H)-ones;    1;    4-Bis(triphenylphosphonium)- 2-butene peroxodisulfate;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

3,4-Dihydropyrimidin-2(1H)-ones were efficiently converted into the corresponding pyrimidin-2(1H)-ones in high yields within a short period of time on treatment with aqueous acetonitrile using 1,4-bis(triphenylphosphonium)- 2-butene peroxodisulfate. Chemoselective oxidation of 3,4-dihydropyrimidin in the presence of other oxidizable functional groups was also achieved by this reagent.

【 授权许可】

Unknown