Study of the Resonance Structures of the Preionizing Spectrum of Molecular Hydrogen by Phase-Shifted Multichannel Quantum Defect Theory II

Bulletin of the Korean chemical society

Chun-Woo Lee¹ 

关键词: Phase-shifted MQDT;    Overlapping resonances;    Preionization of H₂;    Interlopers;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

We obtain the general formulation which can handle the rotational preionization spectrum of H2 in the region above its H2 + ionization threshold (2 +g, v+ = 0, N+ = 0), converging toward its rotationally excited (v+ = 0, N+ = 2) limit and perturbed by the vibrationally excited levels 7pπ v = 1 and 5pπ v = 2. The formulation is based on phase-shifted multichannel quantum-defect theory. With this formulation, resonance structures are analyzed in detail.

【 授权许可】

Unknown