A Practical Synthesis of Morita-Baylis-Hillman Adducts of Aryl Vinyl Ketones Catalyzed by a Proton Donor

Bulletin of the Korean chemical society

Cheol Hee Lim¹   Jae Nyoung Kim¹  Se Hee Kim¹  Sung Hwan Kim¹ 

关键词: Morita-Baylis-Hillman adducts;    Aryl vinyl ketones;    Proton donor;    4-Nitrophenol;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

An efficient and practical synthesis of MBH adducts of aryl vinyl ketones was developed using DABCO and 4-nitrophenol as a proton donor. Addition of a proton donor and the use of excess amounts (3.0 equiv) of aldehydes were highly beneficial for the yields of MBH adducts of aryl vinyl ketones.

【 授权许可】

Unknown