Preparation and Catalytic Application of Pd Loaded Titanate Nanotube: Highly Selective α Alkylation of Ketones with Alcohols

Bulletin of the Korean chemical society

Min Serk Kwon¹  Jae Wook Park¹  Jum Suk Jang¹  Jae Sung Lee¹  Hyun Gyu Kim¹ 

关键词: Hydrothermal synthesis;    Titanate nanotube;    Palladium nanoparticle;    -Alkylation;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The titanate nanotube (TNT) was hydrothermally synthesized in 10 M NaOH aqueous solution at 150 oC for 72 h. Titanate nanotube with high surface area (292 m2/g) is a good candidate as a support for catalytic reaction or organic synthesis. Palladium nanoparticles with an average size of ca. 3 nm were well dispersed onto the surface of TNT nanotubes. Palladium loaded catalyst with high surface area shows a highly efficient α alkylation of ketones with primary alcohols.

【 授权许可】

Unknown