Direct Calculation Method for Excited-state Diffusion-influenced Reversible Reactions with an External Field

Bulletin of the Korean chemical society

Hyojoon Kim¹  Shang Yik Reigh¹ 

关键词: Reversible reaction;    External field;    Reaction-diffusion systems;    Excited state reaction;    Anisotropy;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The direct calculation method is generalized to the excited-state diffusion-influenced reversible reaction of a neutral and a charged particle under an external field with two different lifetimes and quenching in three dimensions. The present method provides an alternative way to calculate the binding probability density functions and the survival probabilities from the corresponding irreversible results. The solutions are obtained as the series solutions by the diagonal approximation due to the anisotropy of the unidirectional external field. The numerical results are found to be in good agreement with those of the previous study [S. Y. Reigh et al. J. Chem. Phys. 132, 164112 (2010)] within a weak field limit. The solutions of two approaches show qualitatively the same overall behavior including the power laws at long times.

【 授权许可】

Unknown