A Novel 3D Polypseudo-rotaxane Metal-organic Framework Based on a Flexible Bis-pyridyl-bis-amide Ligand

Bulletin of the Korean chemical society

Hong-Yan Lin¹  Jian Luan¹  Guo-Cheng Liu¹  Xiu-Li Wang¹  Na Han¹  Chuang Xu¹ 

关键词: Flexible bis-pyridyl-bis-amide ligand;    Polypseudo-rotaxane network;    Hydrothermal synthesis;    Luminescent property;    Cyclic voltammetry;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A novel 3D compound {[Cu(L)(H2O)4][Cu2(SIP)2(L)2]}·2H2O (1) (L = N,N-bis(4-pyridinecarboxamide)-1,4- butane, SIP = 5-sulfoisophthalate) is hydrothermally synthesized. X-ray diffraction analysis reveals that compound 1 is composed of 2D anionic [Cu2(SIP)2(L)2]n 2n− double-layers and discrete 1D cationic [CuL(H2O)4]n 2n+ polymeric chains, which represents a rare 3D polypseudo-rotaxane MOF from intercalation of 1D and 2D framework. In addition, the luminescent property and electrochemical behavior of compound 1 have been investigated.

【 授权许可】

Unknown