Synthesis, Characterization and Structure of DBU-hydrobromide-perbromide: A Novel Oxidizing Agent for Selective Oxidation of Alcohols to Carbonyl Compounds

Bulletin of the Korean chemical society

Mehdi Bakavoli¹  Ali Shiri¹  Reza Takjoo¹  Zahra Ebrahimpour¹  Hossein Eshghi¹  Mohammad Rahimizadeh¹ 

关键词: DBU hydrobromide-perbromide;    Oxidation;    Alcohols;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A new and efficient reagent for the conversion of primary and secondary alcohols into their corresponding aldehydes and ketones is introduced. The reagent was easily prepared from the reaction of DBU with molecular bromine in CHCl3. The structure of the reagent as DBUH+Br3 ? was determined by single crystal X-ray diffraction analysis.

【 授权许可】

Unknown