期刊论文详细信息
Bulletin of the Korean chemical society
Electro-oxidation of Cyclohexanol on a Copper Electrode Modified by Copper-dimethylglyoxime Complex Formed by Electrochemical Synthesis
Nasrin Shadjou1  Isa Kazeman1  Lotfali saghatforoush1  Balal Khalilzadeh1  Mohammad Hasanzadeh1 
关键词: Cyclohexanol;    Electrocatalysis;    Copper dimethylglyoxime;    Alkaline media;   
DOI  :  
学科分类:化学(综合)
来源: Korean Chemical Society
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【 摘 要 】

Copper-dimethylglyoxime complex (CuDMG) modified Copper electrode (Cu/CuDMG) showed a catalytic activity towards cyclohexanol oxidation in NaOH solution. The modified electrode prepared by the dimethylglyoxime anodic deposition on Cu electrode in the solution contained 0.20 M NH4Cl + NH4OH (pH 9.50) and 1 �? 10-4 M dimethylglyoxime. The modified electrode conditioned by potential recycling in a potential range of ?900 ~ 900 mV vs. Ag/AgCl by cyclic voltammetry in alkaline medium (1 M NaOH). The results show that the CuDMG film on the electrode behaves as an efficient catalyst for the electro-oxidation of cyclohexanol in alkaline medium via Cu (III) species formed on the electrode.

【 授权许可】

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