Preparation of Water Soluble Polythiophenes Mediated by Highly Active Zinc

Bulletin of the Korean chemical society

Jong Gyu Kim¹  Seung Hoi Kim¹ 

关键词: Water soluble;    Polythiophenes;    Active zinc;    Polymerization;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A convenient route for the preparation of water soluble polythiophenes is described. Reactions involving highly active zinc metal show unique properties, viz. tolerance of the ester group and regioselectivity to the thiophene ring. Poly [3-(ethyl-n-alkanoate)thiophene-2,5-diyl]s, poly [3-(n-carboxyalkyl)thiophene-2,5-diyl]s, and poly [3-(potassium-n-alkanoate)thiophene-2,5-diyl]s were easily prepared by utilizing highly active zinc.

【 授权许可】

Unknown