Bis(imino)aryl Complex of Nickel(II): N,C,N-Pincer Type Complex,(2,6-(2,6-Et2PhN=CH)2C6H3)NiBr

Bulletin of the Korean chemical society

Dong Hwan Lee¹  Soonheum Park¹  Sungwon J. Hong¹ 

关键词: Bis(imino)aryl;    NCN-Pincer;    Ni(II) NCN-pincer complex;    Oxidative addition;    Catalyst;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The synthesis of a novel N,C,N-type pincer, bis(N-aryl)-2-bromoisophthalaldimine 2,6-(2,6-Et2PhN = CH)2C6H3Br (1) and Ni(1)Br (2) is described. They were characterized by elemental analysis and spectroscopic techniques (IR and 1H NMR). Attempted ethylene polymerization catalyzed by 2 has been futile, leading only to the formation of a small amount of oily oligomers.

【 授权许可】

Unknown