Excited-state Intramolecular Proton Transfer of 1,5- and 1,8-Dihydroxyanthraquinones Chemically Adsorpted onto SiO2, SiO2-Al2O3, and Al2O3 Matrices

Bulletin of the Korean chemical society

Seong Kyu Park¹  Dae Won Cho¹  Ki Seok Jeon¹  Minjoong Yoon¹  Ki Dong Song¹ 

关键词: Excited-state intramolecular proton transfer;    Organic-inorganic hybrid matrix;    Dihydroxyanthraquinone;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

In order to investigate the excited-state intramolecular proton transfer (ESIPT) process of dihydroxyanthraquinones (DHAQ; 1,5-DHAQ and 1,8-DHAQ) in organic-inorganic hybrid matrices, transparent SiO2, SiO2- Al2O3, and Al2O3 matrices chemically bonded with DHAQ were prepared using a sol-gel technique. The absorption maxima of 1,5- and 1,8-DHAQ in SiO2 matrices are observed at around 420 nm, whereas those of DHAQ in both SiO2-Al2O3 and Al2O3 matrices are markedly shifted to longer wavelength compared with those in SiO2 matrix. This indicates that DAHQ forms a chemical bond with an Al atom of Al2O3. The DHAQ in SiO2 matrix shows a markedly Stokes-shifted emission which is originated from the ESIPT in DHAQ. Based on the emission lifetimes of DHAQ, the ESIPT of DHAQ was found to be strongly affected by the chemical interaction with Al atom in the Al2O3-related matrices.

【 授权许可】

Unknown