Endo- and Exo-Coordinated Mercury(II) Complexes of O3S2 Macrocycles:Effect of Dibenzo-Substituents on Coordination Mode

Bulletin of the Korean chemical society

Hyun Jee Kim¹  So Young Lee¹  Jai Young Lee¹  Yongnu Jin¹  Ji-Eun Lee¹  Shim Sung Lee¹ 

关键词: O3S2-Donor macrocycles;    Dibenzo-substituents;    Mercury(II) complex;    Exo- and endo-coordinations;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The reactions of mercury(II) chloride with O3S2-donor macrocyclic ligands with (L1) and without (L2) dibenzosubunit afforded respective exo- (1) and endo-coordinated (2) complexes depending on the ring rigidity of the ligands. From the X-ray crystal structures and comparative NMR studies for the complexes 1 and 2, it is confirmed that the resulting species with different coordination modes exist not only in solid state but also in solution state.

【 授权许可】

Unknown