期刊论文详细信息
Bulletin of the Korean chemical society | |
Endo- and Exo-Coordinated Mercury(II) Complexes of O3S2 Macrocycles: Effect of Dibenzo-Substituents on Coordination Mode |
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Hyun Jee Kim1  So Young Lee1  Jai Young Lee1  Yongnu Jin1  Ji-Eun Lee1  Shim Sung Lee1  | |
关键词: O3S2-Donor macrocycles; Dibenzo-substituents; Mercury(II) complex; Exo- and endo-coordinations; | |
DOI : | |
学科分类:化学(综合) | |
来源: Korean Chemical Society | |
【 摘 要 】
The reactions of mercury(II) chloride with O3S2-donor macrocyclic ligands with (L1) and without (L2) dibenzosubunit afforded respective exo- (1) and endo-coordinated (2) complexes depending on the ring rigidity of the ligands. From the X-ray crystal structures and comparative NMR studies for the complexes 1 and 2, it is confirmed that the resulting species with different coordination modes exist not only in solid state but also in solution state.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912010240315ZK.pdf | 788KB | download |