Fuctionalization of SBA-16 Mesoporous Materials with Cobalt(III) Cage Amine Complex

Bulletin of the Korean chemical society

Sujandi¹  Sang-Eon Park¹  Sang-Cheol Han¹ 

关键词: SBA-16;    Grafting;    Cobalt;    Diaminosarcophagine;    Confinement effect;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Surface modification of tridimensional cubic mesoporous silica, SBA-16, was investigated with pendant arm functionalized cobalt diaminosarcophagine (diAMsar) cage complex which covalently grafted onto the silica surface through the silication with sylanol group. The spectroscopic results showed that the mesoporous structure was preserved under the [Co(diAMsar)]3+ grafting reaction condition. Successful grafting prevented the cobalt diAMsar cage from leaching out from the SBA-16 support.

【 授权许可】

Unknown