Transition Metal-Catalyzed Ortho-Functionalization in Organic Synthesis

Bulletin of the Korean chemical society

Young Jun Park¹  Chul-Ho Jun¹ 

关键词: Transition metal;    Ortho-functionalization;    Chelation-assistance;    C-H bond activation;    Catalysis;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Recent progress in the filed of transition-metal mediated C-H bond activation has had a great influence on organic synthesis. Among such transition-metal catalyzed reactions, ortho-functionalization via the chelationassisted strategy has been paid great attentions as one of the powerful methodologies for converting aromatic compounds into ones that are more functionalized at the exclusively ortho-position. In this context, various transition metal-catalyzed ortho-functionalizations such as alkylation, alkenylation, silylation and carbonylation are described briefly and their prospects are suggested.

【 授权许可】

Unknown