期刊论文详细信息
Bulletin of the Korean chemical society | |
An Efficient Method for Selective Deprotection of Trimethylsilyl Ethers and Tetrahydropyranyl Ethers under Solvent-free Conditions | |
A. R. Hajipour1  Arnold E. Ruoho1  Hamid R. Bagheri1  | |
关键词: Deprotection; Trimethylsilyl ether; Tetrahydropyranyl ethers; Solvent-free; | |
DOI : | |
学科分类:化学(综合) | |
来源: Korean Chemical Society | |
【 摘 要 】
1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAABOD) 3 is a useful reagent for the selective cleavage of trimethylsilyl ethers and tetrahydropyranyl ethers to their corresponding aldehydes and ketones in the presence of AlCl3 under solvent-free conditions. This method is very simple and efficient and the reaction has been carried out under solvent-free conditions in the presence of a catalytically amount of aluminum chloride.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912010239581ZK.pdf | 523KB | download |