An Efficient Method for Selective Deprotection of Trimethylsilyl Ethers and Tetrahydropyranyl Ethers under Solvent-free Conditions

Bulletin of the Korean chemical society

A. R. Hajipour¹  Arnold E. Ruoho¹  Hamid R. Bagheri¹ 

关键词: Deprotection;    Trimethylsilyl ether;    Tetrahydropyranyl ethers;    Solvent-free;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

1-Butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAABOD) 3 is a useful reagent for the selective cleavage of trimethylsilyl ethers and tetrahydropyranyl ethers to their corresponding aldehydes and ketones in the presence of AlCl3 under solvent-free conditions. This method is very simple and efficient and the reaction has been carried out under solvent-free conditions in the presence of a catalytically amount of aluminum chloride.

【 授权许可】

Unknown