Chemoselective Iodination of Alcohols with CeCl3¡¤7H2O/NaI over SiO2 under Microwave Irradiation

Bulletin of the Korean chemical society

Mahmood Tajbakhsh¹  Zahra Lasemi¹  Ali Sharifi¹  Rahman Hosseinzadeh¹ 

关键词: Iodination;    CeCl3¡¤7H2O;    Microwave;    SiO2;    Solvent-free conditions;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A simple and effective procedure for conversion of primary, secondary, allylic and benzylic alcohols into the corresponding iodides is described using CeCl3·7H2O/NaI over SiO2 under microwave irradiation. Benzylic alcohols are selectively converted in the presence of saturated alcohols into their corresponding benzylic iodides under these conditions.

【 授权许可】

Unknown