Concomitant Addition and Acetalization of ¥á, ¥â-Unsaturated Aldehydes with Diols

Bulletin of the Korean chemical society

Chang Kiu Lee¹  Kyu Ok Jeon¹  Ji Sook Yu¹ 

关键词: ¥á;    ¥â-Unsaturated aldehydes;    Acetalization;    Addition;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

α, β-Unsaturated aldehydes such as acrolein and crotonaldehyde were reacted with diols in the presence of conc. sulfuric acid to give products of which concomitant addition to C-C double bond and acetalization took place. Boron trifluoride etherate and titanium tetrachloride gave only acetalization products.

【 授权许可】

Unknown