Synthesis of Neopentyl Biphenylsulfonates Using the Suzuki-Miyaura Reaction

Bulletin of the Korean chemical society

Chul-Hee Cho¹  Myungchul Sun¹  Kwangyong Park¹  Chul-Bae Kim¹ 

关键词: Cross-coupling;    Bromobenzenesulfonates;    Biphenylsulfonates;    Arylboronic acid;    Suzuki-Miyaura reaction;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.

【 授权许可】

Unknown