期刊论文详细信息
Bulletin of the Korean chemical society
Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes
Hee-Cheul Jung1  Yong-Min Lee1  Young-Inn Kim1  Yong-Kyu Kim1  Sung-Nak Choi1 
关键词: (-)-Sparteine;    Oxyanion;    Copper(II);    Interchange reaction.;   
DOI  :  
学科分类:化学(综合)
来源: Korean Chemical Society
PDF
【 摘 要 】

Nine copper(�?) oxyanion, and mixed oxyanion complexes that have four- or five-coordinate geometries around copper(�?) centers were derived from sparteine copper(�?) dinitrate precursor [Cu(C15H26N2)(NO3)2]. The precursor complex undergoes an anion exchange with various oxyanions, and an interchange reaction with other sparteine copper(�?) complexes. The [Cu(C15H26N2)(CH3CO2)2] also undergoes “halogen atom abstraction�? reaction with CCl4 to produce the mixed anion complex [Cu(C15H26N2)(CH3CO2)Cl]. The whole set of prepared complexes has been used for the comparative electrochemical and spectroscopic studies.

【 授权许可】

Unknown   

【 预 览 】
附件列表
Files Size Format View
RO201912010238497ZK.pdf 118KB PDF download
  文献评价指标  
  下载次数:3次 浏览次数:19次