Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes

Bulletin of the Korean chemical society

Hee-Cheul Jung¹  Yong-Min Lee¹  Young-Inn Kim¹  Yong-Kyu Kim¹  Sung-Nak Choi¹ 

关键词: (-)-Sparteine;    Oxyanion;    Copper(II);    Interchange reaction.;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Nine copper(�?) oxyanion, and mixed oxyanion complexes that have four- or five-coordinate geometries around copper(�?) centers were derived from sparteine copper(�?) dinitrate precursor [Cu(C₁₅H₂₆N₂)(NO₃)₂]. The precursor complex undergoes an anion exchange with various oxyanions, and an interchange reaction with other sparteine copper(�?) complexes. The [Cu(C₁₅H₂₆N₂)(CH₃CO₂)₂] also undergoes “halogen atom abstraction�? reaction with CCl₄ to produce the mixed anion complex [Cu(C₁₅H₂₆N₂)(CH₃CO₂)Cl]. The whole set of prepared complexes has been used for the comparative electrochemical and spectroscopic studies.

【 授权许可】

Unknown