Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization

Bulletin of the Korean chemical society

Kyeong Jong Lee¹  Bu Yong Lee¹  Il Yoon¹  Shim Sung Lee¹ 

关键词: Electropolymerization;    Poly-[Fe(3-Br-phen)3]2+;    Glassy carbon disk electrode;    X-Ray crystal structure;    Absorption spectroscopy.;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The complex of iron(�?) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen)₃](PF₆)₂·CH₃CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of [Fe(3-Br-phen)₃]²⁺ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-[Fe(3-Br-phen)₃]²⁺ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.

【 授权许可】

Unknown