Macro-scale complexity of nano- to micro-scale architecture of olivine crystals through an iodine vapour transport mechanism

Bulletin of materials science

Toru Maekawa¹  Takahiro Fukuda¹  Raymond L D Whitby² 

[1] Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, Japan$$Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, JapanBio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, Japan$$;Nanoscience and Nanotechnology Group, Faculty of Science and Engineering, University of Brighton, Lewes Road, Brighton, BN2 4GJ, United Kingdom$$Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, Japan$$Nanoscience and Nanotechnology Group, Faculty of Science and Engineering, University of Brighton, Lewes Road, Brighton, BN2 4GJ, United KingdomNanoscience and Nanotechnology Group, Faculty of Science and Engineering, University of Brighton, Lewes Road, Brighton, BN2 4GJ, United Kingdom$$Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, Japan$$Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, JapanNanoscience and Nanotechnology Group, Faculty of Science and Engineering, University of Brighton, Lewes Road, Brighton, BN2 4GJ, United Kingdom$$Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, 350-8585 Saitama, Japan$$

关键词: Nanocrystals;    forsterite;    fayalite;    iodine vapour transport;    architecture.;   

DOI  :  

学科分类：材料工程

来源: Indian Academy of Sciences

【 摘 要 】

The production of nano- to micro-scale olivine (magnesium and iron silicate) crystals has been achieved at relatively low temperatures through an iodine vapour transport of the metal onto amorphous silicon dioxide. The process occurs down a temperature gradient from 800 to 600°C yielding high quality crystals with long range crystallinity, highly complex interconnectivity and intricate macroscale architecture. Scanning electron microscopy (SEM) imaging of the substrate before and after the reaction reveals that the amorphous silicon oxide species is mobile, due to the lack of correlation between the silicon oxide layer and the final olivine particles, leading to a vapour�?�liquid�?�solid or vapour�?�solid growth mechanism. This technique demonstrates a facile, low temperature synthetic route towards olivine crystals with nano- to micro-scale dimensions.

【 授权许可】

Unknown