XRD and optical microscopic studies of Co(III) complexes containing 5-cyano-6-(4-pyridyl)-2-thiouracil, thymine and adenine bases

Bulletin of materials science

Lallan Mishra¹  R K Mandal²  Brajesh Pathak¹ 

[1] Department of Chemistry, Banaras Hindu University, Varanasi 221 005, India$$Department of Chemistry, Banaras Hindu University, Varanasi 221 005, IndiaDepartment of Chemistry, Banaras Hindu University, Varanasi 221 005, India$$;Department of Metallurgical Engineering, Banaras Hindu University, Varanasi 221 005, India$$Department of Metallurgical Engineering, Banaras Hindu University, Varanasi 221 005, IndiaDepartment of Metallurgical Engineering, Banaras Hindu University, Varanasi 221 005, India$$

关键词: Supramolecular;    hydrogen-bonding;    thymine;    adenine.;   

DOI  :  

学科分类：材料工程

来源: Indian Academy of Sciences

【 摘 要 】

Multifunctional ligand 5-cyano-6-(-4-pyridyl)-2-thiouracil (L) was prepared and allowed to react with trans [Co(en)₂Cl₂]⁺Cl^â€�?? resulting into [Co(en)₂LCl]²⁺.2Cl^â€�?? which upon further reaction with equimolar ratio of ligand [L] gave the complex [Co(en)₂L₂]³⁺.3Cl^â€�??. These metal complexes were then separately reacted with thymine and adenine bases. Complexes thus prepared after characterization by their elemental analysis, FAB mass and spectral (IR, ¹HNMR, UV-visible) data were studied for their powder X-ray diffraction and optical microscopic characteristics.

【 授权许可】

Unknown