Platinum/Nickel Catalyzed Selective Hydrosilylation of Alkynes and Alkenes with 1,1

Journal of the Korean Chemical Society

Jin sik Kim¹  Young Kun Kong¹ 

关键词: 1;    1¡¯-ºñ½ºµð¸ÞÆ¿È÷µå·Î½Ç¸±Æä·Î¼¾;    1;    1¡¯-Bis(dimethylhydrosilyl)ferrocene;    Hydrosilylation;    Dihydrosilylation;    Alkynes;    Alkenes;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The reaction of 1,1¡¯-bis(dimethylhydrosilyl)ferrocene with alkynes in the presence of a catalytic amount of (C2H4)Pt(PPh3)2 leads to the acyclic mixture of monohydrosilylated and/or dihydrosilylated compounds. But the analogous reactions in the presence of Ni(PEt3)4 catalyst yield monohydrosilylated compounds or dihydrosilylated products. The monohydrosilylated products were generated from the reactions of alkenes with the silylated ferrocene using nickel catalyst.

【 授权许可】

Unknown