期刊论文详细信息
Journal of the Korean Chemical Society | |
Structural Characterization of the Eight-Coordinated Dodecahedral Y(tpb) | |
Seong-Joo Kang1  Chongnam Yu1  | |
关键词: dodecahedron; tpb ¥â-diketonate ligand; | |
DOI : | |
学科分类:化学(综合) | |
来源: Korean Chemical Society | |
【 摘 要 】
The eight coordinated yttrium(III) complex Y(tpb)3(H2O)2 (Htpb=4,4,4-Trifluoro-1-phenyl-1,3-butanedione) has been synthesized and structurally characterized by X-ray diffraction method. The coordination polyhedron of Y(tpb)3(H2O)2 has a dodecahedron. The angle between two trapezia, Y-O2-O1-O5-O6 and Y-O4-O3-O8-O7, is 89.59¡Æ. The O1-O5 and O3-O8 distances are 2.965 and 2.995 A whereas the O2-O6 and O4-O7 distances are 4.256 and 4.403 A.
【 授权许可】
Unknown
【 预 览 】
Files | Size | Format | View |
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RO201912010187527ZK.pdf | 407KB | download |