Correlation of Organic Reaction Mechanism with Pressure in S

Journal of the Korean Chemical Society

Se-Kyong Kim¹ 

关键词: Reaction Mechanism;    Rate Constant;    High Pressure;    High Vacuum;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Correlations of organic reaction mechanism with pressure have been studied by kinetics. Various activation parameters were calculated from reaction rate in vacuum and high pressure apparatuses. Besides the change of reaction mechanism were studied from the Hammett -values by changing pressure, temperature and substituent. The relation of thermodynamics with activation volume suggests that the transition state changes upon changing pressures.

【 授权许可】

Unknown