Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)2(Cl)(H2O)]Cl2H2O

Journal of the Korean Chemical Society

Pu Su Zhao¹  Lu De Lu¹  Fang Fang Jian¹ 

关键词: Cobalt Complexes;    1;    10-Phenanthroline Ligands;    Hydrogen Bonds;    Network;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

The crystal structure of [Co(phen)2(Cl)(H2O)] Cl¤ý2H2O(phen=1,10-phenanthroline) has been determined by X-ray crystallography. It crystallizes in the triclinic system, space group P1, with lattice parameters a=9.662(2), b=11.445(1), c=13.037(2)¡Ê ¥á=64.02(1), ¥â=86.364(9), ¥ã=78.58(2)¡Æ, and Z=2. The coordinated cations contain a six-coordinated cobalt atom chelated by two phen ligands and one chloride anion and one water ligand in cis arrangement. In addition to the chloride coordinated to the cobalt, there are one chloride ion and four water molecules which complete the crystal structure. In the solid state, the title compound forms three dimensional network structure through hydrogen bonds, within which exists the strongest hydrogen bond (O(3)-O(4)=2.33¡Ê). The intermolecular hydrogen bonds connect the [Co(phen)2(Cl)(H2O)]1+, H2O moieties and chloride ion.

【 授权许可】

Unknown