C2-Symmetric Val-Val Dipeptide Isosteres via Diethylaluminium Azide Ring Opening of Epoxyalcohols

Croatica Chemica Acta

Benedetti, Fabio¹  Norbedo, Stefano¹  Miertus, Stanislav² 

[1] Department of Chemical Sciences, University of Trieste, Via L. Giorgieri 1, 1-34127 Trieste, Italy;International Centre for Science and High Technology, UNIDO, Trieste, Italy

关键词: diethylaluminium azide;    epoxyalcohol;    diaminodiol dipeptide isostere;    ring opening;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

Diethylaluminium azide has been used as a highly regio- and stereo-selective reagent for the ring opening of valine-derived, sterically hindered epoxyalcohols. This reagent has enabled extending a previously described synthesis of...

【 授权许可】

Unknown