Enantioselectivity of Pseudomonas cepacia Lipase towards 2-Methyl-3(or 4)-arylalkanols: An Approach Based on the Stereoelectronic Theory and Molecular Modeling

Croatica Chemica Acta

Dobovičnik, Vladimir¹  Kojić-Prodić, Biserka¹  Šunjić, Vitomir¹  Tomić, Sanja¹ 

[1] Ruđer Bošković Institute, P. O. Box 180, HR-10002 Zagreb, Croatia

关键词: Pseudomonas cepacia lipase;    kinetic resolution;    primary alcohols;    enantioselectivity;    molecular modeling;    stereoelectronic theory;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

For a better understanding of the previously reported enantioselectivity of Pseudomonas cepacia lipase (PCL) in acylation of racemic primary alcohols, 2-methyl-3(or 4)-arylalkanols, molecular modeling of tetrahedral intermediates (TIs)...

【 授权许可】

Unknown