On the Magnetic Exchange Parameter for an O−Cu−Cu−O Component of CuII Carboxylate Dimers

Croatica Chemica Acta

Harcourt, Richard D.¹ 

[1] School of Chemistry, The University of Melbourne, Victoria 3010, Australia

关键词: copper carboxylate dimer;    antiferromagnetism;    magnetic exchange parameter;    superexchange;    “cis O−O overlap”;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

Two approximate formulae are derived for the magnetic exchange parameter, J = ½{E(singlet) �? E(triplet)}, for an O−Cu−Cu−O component of Cu II carboxylate dimers. The derivations use standard valence bond and molecular orbital...

【 授权许可】

Unknown