Can Transition Metals and Group II Mono- and Dications Discriminate between Homo- and Heterochiral XYYX�? Dimers (X,X�?=H,Me; Y=O,S,Se)?

Croatica Chemica Acta

Mó, Otilia¹  Chen, Kathy J.²  Corral, Inés¹  Yáñez, Manuel¹ 

[1] Departamento de Química, Universidad Autónoma de Madrid, 28049, Cantoblanco, Madrid, Spain;Laboratoire CEISAM - UMR CNRS 6230, Université de Nantes, 2 Rue de la Houssinière, BP 92208, 44322 Nantes Cedex 3, France

关键词: stereoselectivity;    organometallic complex;    chirality;    DFT;    MP2;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

We present a density functional theory and ab initio (MP2) study of stereoisomer discrimination between the homochiral and heterochiral dimers of the form M(XYYX�?)2, where M is a cationic metal (Li+, Ca2+, Zn2+, Cu+, Cu2+) complexing...

【 授权许可】

Unknown