Ring Strain and Other Factors Governing the Basicity of Nitrogen Heterocycles �? An Interpretation by Triadic Analysis

Croatica Chemica Acta

Vianello, Robert¹  Despotović, Ines¹  Radić, Nena¹ 

[1] Quantum Organic Chemistry Group, Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, HR�?10000 Zagreb, Croatia

关键词: Baeyer ring strain;    protonation;    substituent effect;    superbases;    triadic formula;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

M06�?2X/6�?311++G(2df,2pd)//M06�?2X/6�?31+G(d) computations were employed to investigate the intrinsic gas phase basicity of strained nitrogen heterocycles involving aziridine, azetidine, pyrrolidine and piperidine, together with...

【 授权许可】

Unknown