Copper(I) Complexes of N-thiophosphorylated Bis-thiourea [CH2NHC(S)NHP(S)(OiPr)2]2 and Phosphines (PPh3, Ph2P(CH2)1�?3PPh2, Ph2P(C5H4FeC5H4)PPh2): Versatile Structures and Luminescence

Croatica Chemica Acta

Klein, Axel¹  Safin, Damir A.¹  Babashkina, Maria G.¹ 

[1] Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939 Köln, Germany

关键词: coordination chemistry;    copper(I);    thiophosphorylthiourea;    phosphine;    luminescence;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

Reaction of the potassium solution of [CH2NHC(S)NHP(S)(OiPr)2]2 (H2L) with [Cu(PPh3)3I] or a mixture of CuI and Ph2P(CH2)1�?3PPh2 or Ph2P(C5H4FeC5H4)PPh2 in aqueous EtOH/CH2Cl2 leads to binuclear [Cu2(PPh3)2L] (1), [Cu2(Ph2PCH2PPh2)L]...

【 授权许可】

Unknown