The Utility of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as a Hydrogen Bond Acceptor in the Design of Novel Superbasic Guanidines �? A Computational Study

Croatica Chemica Acta

Antol, Ivana¹  Štrukil, Vjekoslav¹  Glasovac, Zoran¹ 

[1]Division of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia

关键词: guanidine;    TBD;    organic superbases;    DFT;    intramolecular hydrogen bond;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

New guanidine-derived superbases with TBD-functionalized alkyl side chains have been developed using a computational DFT approach. Exploiting the high hydrogen bond basicity of TBD allowed ac-cess to systems with strong charge-assisted...

【 授权许可】

Unknown