Kinetics and Mechanism of the Reaction between Mercury(II) and a Series of Macrocyclic Organochromium Cations

Croatica Chemica Acta

Bakač, Andreja¹  Espenson, James H.¹  Butković, Vjera² 

[1] Ames Laboratory, Iowa State University, Ames, Iowa 50011, USA;Ruđer Bosković Institute, P.O. Box 180, 10002 Zagreb, Croatia

关键词: alkylchromium;    electrophilic substitution;    mercury(II);    kinetics;   

DOI  :  

学科分类：化学（综合）

来源: Croatica Chemica Acta

【 摘 要 】

Kinetic data are presented for the reaction of alkylchromium complexes (H 2 O)([14]aneN 4 )CrR 2+ ([14]aneN 4 = 1,4,8,11-tetraazacyclo-tetradecane) with Hg 2+ via electrophilic substitution. The rate constants decrease in the order CH 3...

【 授权许可】

Unknown