Photocatalytic degradation of organic dyes by infinite one dimensional coordination polymer based on Zn(II) in water

Bulletin of The Chemical Society of Ethiopia

W. P. Wu¹ 

关键词: Zn(II);    Coordination polymers;    X-ray;    Photocatalysis;    DOS;   

DOI  :  10.4314/bcse.v33i1.5

学科分类：化学（综合）

来源: Chemical Society of Ethiopia

【 摘 要 】

A new d^10‑based Zn(II) coordination polymer (CP), formulated as [Zn(SO₄)₃(DMF)₃]_n ( 1 ), has been synthesized and structurally characterized. The single crystal X-ray diffraction results indicates that CP 1 forms 1D inorganic –[Zn–SO₄–Zn] _n – chain along the ac plane. The thermal stability, UV/Vis diffuse-reflection spectrum and photocatalytic behavior of 1 against organic dyes have been investigated. The photocatalysis results indicate that 1 displays better photocatalytic activities against RhBin comparison toMV. The probable mechanism associated with the photocatalysis of 1 against organic dyes has been addressed using density of states (DOS) calculations.

【 授权许可】

Unknown