sp2 carbon allotropes in elastomer matrix: From master curves for the mechanical reinforcement to lightweight materials

eXPRESS Polymer Letters

M. Galimberti¹ 

关键词: rubber;    carbon nanotubes;    interfacial area;    lightweight material;    dynamic moduli;   

DOI  :  10.3144/expresspolymlett.2018.24

学科分类：生物科学（综合）

来源: eXPRESS Polymer Letters

【 摘 要 】

This work presents high surface area sp2 carbon allotropes as important tools to design and prepare lightweightmaterials. Composites were prepared based on either carbon black (CB) or carbon nanotubes (CNT) or hybrid CB/CNTfiller systems, with either poly(1,4-cis-isoprene) or poly(styrene-co-butadiene) as the polymer matrix. A correlation was establishedbetween the specific interfacial area (i.a.), i.e. the surface made available by the filler per unit volume of composite,and the initial modulus of the composite (G′γmin), determined through dynamic mechanical shear tests. Experimental pointscould be fitted with a common line, a sort of master curve, up to about 30.2 and 9.8 mass% as CB and CNT content, respectively.The equation of such master curve allowed to correlate modulus and density of the composite. Thanks to the mastercurve, composites with the same modulus and lower density could be designed by substituting part of CB with lower amountof the carbon allotrope with larger surface area, CNT. This work establishes a quantitative correlation as a tool to designlightweight materials and paves the way for large scale application in polymer matrices of innovative sp2 carbon allotropes.

【 授权许可】

CC BY