Quimica nova | |
SEPARATION OF ZINC FROM MANGANESE BY SOLVENT EXTRACTION FROM ACIDIC LEACHATES OF SPENT ZINC-MnO2 DRY CELLS USING NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS | |
Afonso, Júlio Carlos1  Ibiapina, VinÃcio Francisco2  | |
[1] Instituto de Engenharia Nuclear, Rio de Janeiro, Brasil;Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brasil | |
关键词: Zinc-MnO2 dry cells; acid leaching; zinc extraction; neutral organophosphorus extractants; manganese oxalate; sodium salts.; | |
DOI : 10.21577/0100-4042.20170249 | |
学科分类:化学(综合) | |
来源: Sociedade Brasileira de Quimica | |
【 摘 要 】
This paper describes a route for recovering manganese and zinc from spent zinc-MnO2 dry cells via acid leaching using sulfuric or hydrochloric acids as leachants. Hydrogen peroxide was added as reductant. Experiments were run at 25-40 °C for 1-3 h. Under the best optimal conditions, over 97.5 wt.% of zinc and manganese were leached by both acids. Zn(II) was best extracted at high free acidity (≥ 1 mol L-1) with tributylphosphate (TBP) or trialkylphosphine oxides (Cyanex 923) diluted in n-heptane. Cyanex 923 was a better extractant than TBP, and the extraction was better performed in hydrochloric leachates. Mn(II) was more co-extracted from hydrochloric leachates and when Cyanex 923 was the extractant, but was easily scrubbed with dilute leachant (~1-2 mol L-1). Zn(II) striping was possible using 5 mol L-1 HCl or H2SO4. Manganese was precipitated as oxalate (MnC2O4.2H2O), free of leached contaminants. High-purity sodium salts of the anions of the leachants were recovered after slow evaporation of the final solution.
【 授权许可】
CC BY
【 预 览 】
Files | Size | Format | View |
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RO201910259661877ZK.pdf | 980KB | download |