The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di­methyl­hydrazin-1-yl­idene)meth­yl]-1′-(di­phenyl­phospho­rothio­yl)ferrocene

Acta Crystallographica Section E: Crystallographic Communications

Mouas, T.N.¹  Merazig, H.²  Daran, J.-C.³ 

[1] CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France;Dpartement de Biochimie et Bio Mol Cell, Laboratoire de Gntique, Biochimie et Biotechnologie Vgtale, Universit Constantine 1, Algeria;Unit de Recherche de Chimie de l'Environnement et Molcule Structurales, CHEMS, Universit Constantine 1, Algeria

关键词: CRYSTAL STRUCTURE;    FERROCENYL P,N LIGANDS;    THIOPHOSPHINE;    HYDRAZINE;    CATALYSIS;    HYDROGEN BONDING;    C-H...[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989018000440

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title compound, [Fe(C8H11N2)(C17H14PS)], contains two independent mol­ecules (A and B) with very similar conformations. Each mol­ecule is built up from a ferrocene unit substituted in the 1 and 1′ positions by a protected sulfur di­phenyl­phosphine and by a di­methyl­hydrazine, –C(H)=N—N(CH3)2, fragment. The two independent mol­ecules are linked by a C—H⋯N hydrogen bond. In the crystal, the A–B dimer is linked by a pair of C—H⋯S hydrogen bonds, forming a centrosymmetric four-mol­ecule arrangement. These units are linked by C—H⋯π inter­actions, forming a supra­molecular three-dimensional structure.

【 授权许可】

CC BY