Crystal structure of the lead-containing organic–inorganic hybrid: (C18H26N2)3[Pb4I14(DMSO)2]·2DMSO

Acta Crystallographica Section E: Crystallographic Communications

Zhao, D.¹  Li, L.² 

[1] School of Chemistry and Environmental Engineering, Shandong University of Science and Technology, Qingdao, People's Republic of China;State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of China

关键词: ORGANIC-INORGANIC HYBRID;    CRYSTAL STRUCTURE;    HYDROGEN-BONDING INTERACTIONS;    [PI]-[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989018016584

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, tris­(1,1′-dibutyl-4,4′-bi­pyridine-1,1′-diium) bis­(dimethyl sulfoxide)di-μ3-iodido-tetra-μ2-iodido-octa­iodido­tetra­lead(II) dimethyl sulfoxide di­solvate, (C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H⋯O and C—H⋯I hydrogen-bonding inter­actions, π–π inter­actions, other short contacts and Pb octa­hedral chains are present, extending the crystal structure into a three-dimensional supra­molecular network.

【 授权许可】

CC BY