Crystal structure of tri­benzyl­bis­(tetra­hydro­furan-κO)lutetium(III)

Acta Crystallographica Section E: Crystallographic Communications

Saliu, K.O.¹ 

[1] Department of Chemistry, University of Alberta, Edmonton, AB T6G 2G2, Canada

关键词: LANTHANIDE;    LUTETIUM;    PENTACOORDINATE;    BENZYL;    CRYSTAL STRUCTURE;   

DOI  :  10.1107/S2056989017018254

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, [Lu(C7H7)3(C4H8O)2] (1), the Lu ion is coordinated by three benzyl and two tetra­hydro­furan ligands. Two of the benzyl groups are bonded in a classical η1-fashion through the methyl­ene via the ipso-carbon atom of the benzyl ligand in addition to bonding through the methyl­ene C atom, resulting in a modified trigonal–bipyramidal coordination geometry about the Lu center.

【 授权许可】

CC BY