Effects of Ionic Strength on Arsenate Adsorption at Aluminum Hydroxide–Water Interfaces

Soils

Catalano, Jeffrey G.¹  Xu, Tingying² 

[1] Author to whom correspondence should be addressed.;Department of Earth and Planetary Sciences, Washington University, 1 Brookings Drive, Saint Louis, MO 63130, USA

关键词: arsenate adsorption;    ionic strength;    inner-sphere adsorption;    outer-sphere adsorption;    adsorption isotherm;    EXAFS spectroscopy;   

DOI  :  10.3390/soils2010001

学科分类：土壤学

来源: mdpi

【 摘 要 】

Adsorption processes at mineral–water interfaces control the fate and transport of arsenic in soils and aquatic systems. Mechanistic and thermodynamic models to describe this phenomenon only consider inner-sphere complexes but recent observation of the simultaneous adsorption of inner- and outer-sphere arsenate on single crystal surfaces complicates this picture. In this study, we investigate the ionic strength-dependence of the macroscopic adsorption behavior and molecular-scale surface speciation of arsenate bound to gibbsite and bayerite. Arsenate adsorption decreases with increasing ionic strength on both minerals, with a larger effect at pH 4 than pH 7. The observed pH-dependence corresponds with a substantial decrease in surface charge at pH 7, as indicated by ζ-potential measurements. Extended X-ray absorption fine structure (EXAFS) spectroscopy finds that the number of second shell Al neighbors around arsenate is lower than that required for arsenate to occur solely as an inner-sphere surface complex. Together, these observations demonstrate that arsenate displays macroscopic and molecular-scale behavior consistent with the co-occurrence of inner- and outer-sphere surface complexes. This demonstrated that outer-sphere species can be responsible for strong adsorption of ions and suggests that environments experiencing an increase in salt content may induce arsenic release to water, especially under weakly acidic conditions.

【 授权许可】

CC BY