Characterization of Tar Deposits, Extraction and Sorption Properties

GeoScience Engineering

关键词: Tar deposits;    characterization;    extraction;    adsorption;   

DOI  :  10.1515/gse-2016-0010

学科分类：地球科学(综合)

来源: De Gruyter

【 摘 要 】

The main goal of this paper was to characterize and find a useful solution for the decomposition of tar deposits. For the experimental part, tar deposits, formed by polymerization and condensation reactions, were chosen from a storage tank for tars. At first the initial analyses of tar deposits (elemental, thermogravimetric, and calorimetric analyses) were performed. After the characterization, the tar deposits were extracted in the Soxhlet extractor by acetone, toluene, and quinolone and activated with potassium hydroxide. As the final step of this work, the sorption characterization on the 3Flex Surface Characterization Analyzer (Micromeritics) was performed. The specific surface area of the samples was evaluated using two methods - a single point measurement at p/p0=0.2 and BET method. Micropore and external surface areas were calculated based on a t-plot analysis (carbon black model).

【 授权许可】

Unknown