A new nitrogen-containing carbon nanoparticle coated stainless steel fiber for selective solid-phase microextraction of ultraviolet filters

Analytical methods

Mei Guo²  Wen-lan Song²  Yi-da Zhang²  Xin-zhen Du³ 

[1]Environmental Analysis of Gansu,Lanzhou 730070,P. R. China

[2]College of Chemistry and Chemical Engineering, Northwest Normal University,Lanzhou 730070,P. R. China

[3]College of Chemistry and Chemical Engineering, Northwest Normal University,Lanzhou 730070,P. R. ChinaKey Lab of Bioelectrochemistry &

DOI  :  10.1039/C5AY00009B

学科分类：分析化学

来源: Royal Society of Chemistry

【 摘 要 】

A new nitrogen-containing carbon nanoparticle (N-CNP) coated fiber was developed for solid phase microextraction (SPME) with direct electrodeposition of a polyaniline coating on etched stainless steel wire using a potentiostatic technique followed by carbonization at 500 °C under a nitrogen atmosphere. The extraction performance of the N-CNP coating was investigated towards polycyclic aromatic hydrocarbons (PAHs), ultraviolet (UV) filters and phthalate acid esters (PAEs) in water samples coupled to high performance liquid chromatography with UV detection (HPLC-UV). This N-CNP coating shows excellent selectivity for UV filters compared to that for PAHs and PAEs. Under optimized conditions, the linearity of UV filters was in the range of 0.02–200 μg L−1 with a corresponding correlation coefficient of 0.9921–0.9993. The recoveries ranged from 89.2% to 119%. The relative standard deviations of a single fiber were between 4.83% and 7.82% (n = 5) and fiber-to-fiber were between 7.94% and 10.14% (S/N = 3). Their limits of detection and the limits of quantitation ranged from 0.006–0.203 μg L−1 and 0.02–0.67 μg L−1, respectively. The proposed SPME-HPLC-UV procedure was successfully used for the selective concentration and sensitive determination of UV filters in environmental water samples. Furthermore, this new robust fiber was easily prepared in a reproducible manner...

【 授权许可】

CC BY-NC