Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne

Acta Crystallographica Section E: Crystallographic Communications

Thekku Veedu, S.¹  Techert, S.³ 

[1]FS–

[2]Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, 37077 Gö

[3]SCS, Deutsches Elecktronen-Synchrotron (DESY), Notkestrasse 85, 22607 Hamburg, Germany

[4]ttingen, Germany

关键词: CRYSTAL STRUCTURE;    PYRENE;    DONOR ACCEPTOR;    ELECTRON TRANSFER;    C-H...[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989015013729

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, C34H37N, is a pyrene derivative in which the pyrene ring system is linked to an ethyl­cyclo­hexane unit which, in turn, carries a [4-(di­methyl­amino)­phen­yl]ethyl substituent in the para position. The central cyclo­hexane ring has a chair conformation, with the exocyclic C—C bonds in equatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation = 0.038 (4) Å] by 14.84 (15)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)].

【 授权许可】

CC BY