Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc

Acta Crystallographica Section E: Crystallographic Communications

Reddy, D.S.¹  Thirumurugan, S.¹  Anbalagan, K.¹  Govindaraj, J.²  SubbiahPandi, A.³ 

[1] Department of Chemistry, Pondicherry University, Pondicherry 605 014, India;Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India;Department of Physics, Presidency College (Autonomous), Chennai 600 005, India

关键词: CRYSTAL STRUCTURE;    ZINC COMPLEX;    TETRAHEDRAL COORDINATION;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989014027832

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl­aniline. The Zn2+ cation is coordinated by two Cl− anions and the N atoms of two 4-ethyl­aniline ligands, forming a distorted Zn(N2Cl2) tetra­hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N—H⋯Cl hydrogen bonds link the mol­ecules into sheets perpendicular to the a axis. C—H⋯Cl inter­actions also occur.

【 授权许可】

CC BY