Synthesis and crystal structure of a new alluaudite-like iron phosphate Na2CaMnFe(PO4)3

Acta Crystallographica Section E: Crystallographic Communications

Badri, A.²  Jebli, S.⁴  Ben Amara, M.⁵ 

[1] de Monastir, 5019, Monastir, Tunisia;de Recherche, Matédes Sciences, UniversitéUnitériaux Inorganiques, Faculté

关键词: XRD;    IRON PHOSPHATE;    ALLUAUDITE STRUCTURE;    CRYSTAL STRUCTURE;   

DOI  :  10.1107/S2056989016017771

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na2CaMnFe(PO4)3, has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it obeys the X(2)X(1)M(1)M(2)2(PO4)3 general formula. Both the X(2) and X(1) sites are fully occupied by sodium, while M(1) is occupied by calcium and M(2) exhibits a statistical distribution of iron and manganese.

【 授权许可】

CC BY