Crystal structure of di-μ2-chlorido-bis­[(1-aza-4-azoniabi­cyclo­[2.2.2]octane-κN1)di­chlorido­dicadmium]

Acta Crystallographica Section E: Crystallographic Communications

Pan, Q.-J.¹  Yan, J.-J.¹  Chen, L.-Z.¹ 

[1]School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, People's Republic of China

关键词: CRYSTAL STRUCTURE;    CADMIUM;    DABCO;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015023361

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the structure of the binuclear title compound, [Cd2(C6H13N2)2Cl6], two CdII atoms are bridged by two Cl− ligands, defining a centrosymmetric Cd2Cl2 motif. Each metal cation is additionally coordinated by two Cl− ligands and the N atom of a protonated 1,4-di­aza­bicyclo­[2.2.2]octane (H-DABCO)+ ligand, leading to an overall trigonal–bipyramidal coordination environment with one of the bridging Cl− ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linked via N—H⋯Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100).

【 授权许可】

CC BY